尹宇, 马兴华, 张树玲, 夏俊佳. 激光熔覆稀土添加金属基涂层研究现状[J]. 金属加工(热加工), 2024, (1): 110-120. DOI: 10.3969/j.issn.1674-165X.2024.01.024
引用本文: 尹宇, 马兴华, 张树玲, 夏俊佳. 激光熔覆稀土添加金属基涂层研究现状[J]. 金属加工(热加工), 2024, (1): 110-120. DOI: 10.3969/j.issn.1674-165X.2024.01.024
Research status of laser cladding metal-based coatings with rare earth addition[J]. MW Metal Forming, 2024, (1): 110-120. DOI: 10.3969/j.issn.1674-165X.2024.01.024
Citation: Research status of laser cladding metal-based coatings with rare earth addition[J]. MW Metal Forming, 2024, (1): 110-120. DOI: 10.3969/j.issn.1674-165X.2024.01.024

激光熔覆稀土添加金属基涂层研究现状

Research status of laser cladding metal-based coatings with rare earth addition

  • 摘要: 利用激光熔覆技术制备表面强化涂层是提高材料服役性能的重要途径之一,即可根据服役环境要求,通过改变熔覆工艺来调控涂层成分、组织结构,从而改善其性能,延长零部件的使用寿命.近年来,在涂层中掺杂稀土元素是激光熔覆领域的研究热点之一.稀土元素拥有特殊的电子结构,能净化合金溶液、细化晶粒;适当添加稀土元素可以有效地降低稀释率,细化熔覆层晶粒,降低孔隙率,以及缓解残余热应力,从而降低涂层的裂纹敏感性.因此,添加稀土元素的涂层具有更好的强度、韧性、耐蚀性和耐磨性.设计含有不同种类(成分)稀土元素的金属基涂层,并结合适宜的激光熔覆参数,有望成为极端环境下机械装备和关键部件表面强化的理想手段.通过总结3种常用稀土氧化物(氧化镧、氧化铈和氧化钇)作用为出发点,综述稀土元素对金属基涂层的微观组织及性能的影响研究,并对其在表面工程领域亟待解决的问题和未来发展方向进行了展望.

     

    Abstract: Fabrication of surface strengthening coating using laser cladding is one of the important ways to improve the materials service performance.According to the requirement of service environment,the performance can be improved and service life can be elongated of the work pieces by regulating the compositions and microstructures of cladding coatings through adjusting the laser cladding parameters.Recent years,doping rare earth has been one of the research hotspots in laser cladding field.Rare earth elements have special electronic structure,which can purify the alloy solution and refine the grains.The appropriate addition of rare earth can effectively reduce the dilution rate,refine the grain size,decrease the porosity and release the residual thermal stress,thus reducing the crack sensitivity of the cladding layer.Therefore,the coatings with rare earth have better strength,toughness,corrosion resistance and wear resistance.Designing metal-based coatings with different types of rare earth addition and combining with appropriate laser cladding parameters are expected to be an ideal method for surface strengthening in extreme environment.In this paper,the effects of three common rare earth oxides(lanthanum oxide,cerium oxide and yttrium oxide)are summarized,and the latest research results of rare earth reinforced metal-based laser cladding coatings are introduced detail,and the crucial problems to be solved in the field of surface engineering and the future development direction are prospected.

     

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