大线能量焊接船用钢接头的腐蚀行为与组织关联机制

Corrosion Behavior and Its Microstructure-Related Mechanism in High-Heat-Input Welded Marine Steel Joints

  • 摘要: 针对60 mm厚EH36、EH40船用高强钢大线能量焊接接头在海洋环境中的耐蚀性问题,选取EH36进口焊丝接头、EH36国产焊丝接头和EH40进口焊丝接头为研究对象,采用动电位极化和电化学阻抗谱测试其在3.5% NaCl溶液中的电化学腐蚀行为,并结合光学显微镜和扫描电镜分析不同接头的显微组织特征,探讨焊接接头耐蚀性的组织影响机制。结果表明:3组接头焊缝区域耐蚀性大小规律为EH36进口>EH36国产>EH40进口。EH36进口接头的腐蚀电流密度最低,为6.9024 μA·cm-2,极化电阻最高,为3525.7 Ω·cm2,表现出最佳耐蚀性;EH36国产接头的自腐蚀电位最正,为-0.396 V,但其综合腐蚀动力学性能略低于EH36进口;EH40进口接头腐蚀电流密度最高,耐蚀性相对最差。组织分析表明,EH36进口接头热影响区晶粒较细且分布均匀,焊缝区针状铁素体致密交织,夹杂物细小弥散,焊缝、热影响区与母材之间组织衔接较好;EH36国产接头存在局部粗晶、夹杂尺寸偏大和组织分布不均现象;EH40进口接头虽焊缝成形较好,但热影响区组织均匀性和针状铁素体分布状态不及EH36进口。研究表明,晶粒细化、夹杂物弥散化及针状铁素体的有效形成是提高大线能量焊接船用钢接头耐蚀性的关键组织因素。

     

    Abstract: To investigate the corrosion resistance of high-heat-input welded joints of 60 mm-thick EH36 and EH40 shipbuilding steels in marine environments, three types of joints, namely EH36 joints welded with imported flux-cored wire, EH36 joints welded with domestic flux-cored wire, and EH40 joints welded with imported flux-cored wire, were selected. Potentiodynamic polarization and electrochemical impedance spectroscopy were employed to evaluate their electrochemical corrosion behavior in 3.5% NaCl solution. Optical microscopy and scanning electron microscopy were used to characterize the microstructures of the joints, and the microstructure-related mechanism affecting corrosion resistance was discussed. The results show that the corrosion resistance of the weld zones follows the order of EH36 imported > EH36 domestic > EH40 imported. The EH36 joint welded with imported wire exhibits the lowest corrosion current density of 6.9024 μA·cm-2 and the highest polarization resistance of 3525.7 Ω·cm2, indicating the best corrosion resistance. The EH36 joint welded with domestic wire shows the most positive corrosion potential of -0.396 V, but its overall corrosion kinetic performance is slightly inferior to that of the imported EH36 joint. The EH40 joint welded with imported wire presents the highest corrosion current density and the lowest corrosion resistance. Microstructural analysis indicates that the EH36 imported joint possesses relatively fine and uniform grains in the heat-affected zone, densely interwoven acicular ferrite in the weld zone, finely dispersed inclusions, and better microstructural compatibility among the weld metal, heat-affected zone and base metal. In contrast, the EH36 domestic joint shows local coarse grains, larger inclusions and non-uniform microstructure, while the EH40 imported joint, despite its good weld formation, exhibits poorer microstructural uniformity and acicular ferrite distribution than the EH36 imported joint. The results demonstrate that grain refinement, inclusion dispersion and effective acicular ferrite formation are the key microstructural factors for improving the corrosion resistance of high-heat-input welded joints of shipbuilding steels.

     

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