Mn元素对CuZnNi钎料润湿性能及钎焊接头组织和性能的影响

Effect of Mn element on the wettability of CuZnNi brazing filler metal and the microstructure and properties of brazed joints

  • 摘要: 将不同Mn元素含量加入CuZnNi钎料中,研究CuZnNiMnx钎料的熔点、润湿铺展性能和微观组织构成。采用CuZnNiMnx钎料感应钎焊YG8硬质合金和Q235钢,研究不同Mn含量对感应钎焊接头微观组织构成及抗拉强度的影响。结果表明:随着Mn含量从0增加至6wt.%,CuZnNiMnx钎料的固液相线分别从1014.45℃降低至915.88℃,钎料润湿铺展性能提高,其在钢表面的润湿铺展面积从210mm2增加至310mm2。CuZnNiMnx钎料基体微观组织主要由α-Cu固溶体和β(β’)Cu-Zn固溶体构成,钎料中Mn含量的增加改变了组织中两中物相比例和形态。当钎料中Mn含量为6wt.%时,两种物相产生偏析。YG8硬质合金和Q235钢感应钎焊接头主要由钎缝界面区的Co-Cu-Ni的固溶体和钎缝中心富Cu的α-Cu固溶体和富Zn的Cu-Zn合金构成。随着Mn含量的增加,钎焊接头的抗拉强度从增加后减小,当Mn含量为4wt.%时,钎焊接头的抗拉强度值达到最大为325MPa。

     

    Abstract: Element Mn with different contents were added into CuZnNi brazing filler metals, and the melting point, wetting and spreading properties and microstructure composition of CuZnNiMnx brazing filler metals were studied. Subsequently, the CuZnNiMnx brazing filler metal was used to induction braze YG8 hard alloy and Q235 steel and the effect of different Mn contents on the microstructure composition and tensile strength of the brazed joint were discussed. The results showed that when the Mn content increased from 0 to 6 wt.%, the solid-liquid phase lines of CuZnNiMnx brazing filler metal decreased from 1014.45℃ to 915.88℃, so that the wetting and spreading properties of the brazing filler metal improved. The wetting and spreading area of CuZnNiMnx brazing filler metal on the steel surface increased from 210mm2 to 310mm2. The microstructure of CuZnNiMnx brazing filler metal was mainly composed of α-Cu solid solution and β(β ')Cu-Zn solid solution. With the increase of Mn content, the proportion of α-Cu solid solution decreased and the proportion of β (β ') Cu-Zn solid solution increased. When the Mn content increased to 6wt.%, the two kinds of phase generated segregation. The induction brazed joint between YG8 hard alloy and Q235 steel was mainly composed of Co-Cu-Ni solid solution in the interface of brazing seam and YG8 hard alloy, also α-Cu solid solution and Cu-Zn alloy in the brazing seam center. The tensile strength of the brazed joint increased first and then decreased with the Mn content increasing. When the Mn content was 4 wt.%, the tensile strength of the brazed joint reached the maximum value of 325 MPa.

     

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