Inconel 625熔覆金属在MgCl2-KCl熔盐中的高温腐蚀行为及元素扩散模型构建

High temperature corrosion behavior and element diffusion model construction of Inconel 625 clad metal in MgCl2-KCl molten salt

  • 摘要: Inconel 625药芯焊丝因其具有优异的耐腐蚀性,广泛应用于太阳能储能管道的修补工作中。在含高温氯化物熔盐管道的应用环境中,修补后的管道表面容易沉积盐膜,导致高温热腐蚀。本文为了研究Inconel 625熔覆金属的热腐蚀机理,利用MAG焊堆出Inconel 625熔覆金属。探究600℃-800℃下Inconel 625熔覆金属在MgCl2–KCl熔盐中的腐蚀行为。研究表明,Inconel 625熔覆金属的晶格常数随着温度的升高而降低。同时本文建立了Inconel 625熔覆金属的元素扩散模型来描述Cl、Ni、Cr元素腐蚀后的扩散行为。基于偏微分方程和初始边界条件对扩散模型进行了模拟。通过计算得出在800°C下Cl、Ni、Cr元素在Inconel 625熔覆金属中的扩散系数分别为7.68 ×10-14 cm2·s-1、6.78 ×10-14 cm2·s-1和7.34 ×10-14 cm2·s-1。Inconel 625熔敷金属被氯化物熔盐腐蚀主要与Cr元素的扩散溶解以及Cl-的侵入有关,扩散系数越大,其耐腐蚀性越差。

     

    Abstract: Inconel 625 flux cored welding wire is widely used in the repair of solar energy storage pipelines due to its excellent corrosion resistance. In the application environment of high-temperature chloride molten salt pipelines, the repaired pipeline surface is prone to salt film deposition, leading to high-temperature thermal corrosion. In order to study the hot corrosion mechanism of Inconel 625 overlay metal, MAG welding was used to stack Inconel 625 overlay metal. Explore the corrosion behavior of Inconel 625 clad metal in MgCl2-KCl molten salt at 600 ℃ -800 ℃. Research has shown that the lattice constant of Inconel 625 deposited metal decreases with increasing temperature. At the same time, this article establishes an element diffusion model for Inconel 625 clad metals to describe the diffusion behavior of Cl, Ni, and Cr elements after corrosion. The diffusion model was simulated based on partial differential equations and initial boundary conditions. The diffusion coefficients of Cl, Ni, and Cr elements in Inconel 625 clad metal at 800 ° C were calculated to be 7.68 × 10-14 cm2·s-1, 6.78 × 10-14 cm2·s-1, and 7.34 × 10-14 cm2·s-1, respectively. The corrosion of Inconel 625 deposited metal by chloride molten salt is mainly related to the diffusion and dissolution of Cr element and the invasion of Cl-. The higher the diffusion coefficient, the worse its corrosion resistance.

     

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