回流时间对Sn0.3Ag0.7Cu/Cu焊点界面金属间化合物生长行为的影响

The effect of reflow time on the growth behavior of intermetallic compounds at the interface of Sn0.3Ag0.7Cu/Cu solder joints

  • 摘要: 通过瞬时液相扩散焊工艺制备Cu/Sn0.3Ag0.7Cu/Cu复合焊点,采用扫描电镜和能谱仪研究回流时间对Sn0.3Ag0.7Cu/Cu焊点界面金属间化合物(IMC)组织形貌和生长动力学的影响。结果表明:在回流温度不变的情况下,Sn0.3Ag0.7Cu/Cu焊点界面金属间化合物层厚度与回流时间正相关,随着回流时间增加,Cu/Sn0.3A g0.7Cu/Cu焊点金属间化合物层厚度逐渐增加,焊点金属间化合物的形貌由锯齿状向扇贝状转变。当回流时间为12h时,冷热两端金属间化合物生长到一起,Sn元素在钎料基体中的完全反应导致Cu6Sn5相转变为Cu3Sn相,相变引起的体积收缩使焊缝产生缺陷。冷端金属间化合物的生长速度大于热端,冷热两端金属间化合物的扩散系数分别为0.568μm2/h和0.019μm2/h。冷端金属间化合物的生长处于反应控制阶段,金属间化合物的生长受Cu原子扩速率影响,热端金属间化合物的生长处于晶界扩散控制阶段,金属间化合物的生长受Cu原子穿越晶界速率的影响,生长极为缓慢。焊接接头的抗剪强度由34.54MPa降至20.99MPa,降低了39.2%。

     

    Abstract: Cu/Sn0.3Ag0.7Cu/Cu composite solder joints were prepared by transient liquid phase diffusion bonding process.The effects of reflow time on the microstructure and growth kinetics of intermetallic compounds at the interface of Sn0.3Ag0.7Cu/Cu solder joints were studied by scanning electron microscopy and energy dispersive spectroscopy.The results show that the thickness of intermetallic compound (IMC) at the interface of Sn0.3Ag0.7Cu/Cu solder joint is positively correlated with the reflux time when the reflux temperature is constant.With the increase of reflux time,the thickness of IMC layer in Cu/Sn0.3Ag0.7Cu/Cu solder joint increases gradually,and the morphology of intermetallic compound in solder joint changes from serrated to scalloped.When the reflow time is 12h,the IMC grow together at the hot and cold ends.The complete reaction of Sn element in the solder matrix leads to the transformation of Cu6Sn5 phase into Cu3Sn phase,and the volume shrinkage caused by the phase transformation causes defects in the weld.The growth rate of IMC at the cold end is greater than that at the hot end.The diffusion coefficients of IMC at the cold and hot ends are 0.568μm~2/h and 0.019μm~2/h,respectively.The growth of the cold end IMC is in the reaction control stage,the growth of the IMC is affected by the diffusion rate of Cu atoms,and the growth of the hot end IMC is controlled by grain boundary diffusion.The growth of IMC is affected by the rate of Cu atoms passing through the grain boundary,and the growth is extremely slow.The shear strength of the welded joint was reduced from 34.54MPa to 20.99MPa,which was reduced by 39.2%.

     

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