In 和Ni对银基钎料的组织和性能影响

Effects of In and Ni on the microstructure and properties of silver-based brazing alloys

  • 摘要: 研究用 In 和Ni替代 Ag20CuZn钎料Ag元素,改善Ag20CuZn钎料的同时降低钎料的成本。研究改良后的钎料对冰箱制冷系统中的不锈钢毛细管和紫铜毛细管的焊接性能和组织的影响。采用DSC差示扫描量热技术分析钎料的固、液相线温度,使用3D激光测量仪测试钎料在304不锈钢上的润湿性,利用扫描电镜、能谱分析、XRD分析等分析方法,观察In 和Ni替代 Ag20CuZn钎料中Ag元素对合金微观组织的影响;采用材料万能试验机测试测试钎料焊接不锈钢/Cu接头抗剪强度。添加适量In 和Ni替代 Ag20CuZn钎料中Ag元素可以降低钎料的固液相线温度,提高钎料对304不锈钢的润湿性。当In和Ni含量分别为1.2 wt%和1.8wt%时,微观组织细化效果最为明显,焊接接头抗剪强度最好。使用Ag17CuZn-1.8Ni-1.2In钎料焊接不锈钢毛细管和紫铜管,满足冰箱制冷系统中毛细管的焊接要求。

     

    Abstract: The study involves replacing the Ag element in Ag20CuZn solder with In and Ni to improve the Ag20CuZn solder while reducing its cost. It also investigates the impact of the modified solder on the welding performance and microstructure of stainless steel capillaries and red copper capillaries in refrigerator refrigeration systems.The differential scanning calorimetry (DSC) technique is used to analyze the solidus and liquidus temperatures of the solder. A 3D laser measuring instrument is employed to test the wettability of the solder on 304 stainless steel. Analytical methods such as scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) are utilized to observe the influence law of In and Ni replacing Ag in Ag20CuZn solder on the microstructure of the alloy. Additionally, a universal testing machine is used to test and analyze the shear strength of the stainless steel/Cu joints welded with the solder. The partial replacement of Ag in Ag20CuZn with In and Ni effectively reduced the solidus and liquidus temperatures of the filler metal while enhancing the wettability of the silver-based filler metal on 304 stainless steel. When the In and Ni contents were 1.2 wt% and 1.8 wt%, respectively, the most significant refinement of the microstructure was observed. Additionally, tThe welded joint exhibits the highest shear strength. The brazing of stainless steel capillary tubes and copper tubes using Ag17CuZn-1.8Ni-1.2In filler metal meets the welding requirements for capillary tubes in refrigerator refrigeration systems.

     

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