预时效对镍基高温合金双峰γ′结构和热加工性能的影响

Effect of Pre-aging on Bimodal γ′ Structure and Hot Workability of Nickel-Based Superalloy

  • 摘要: 本文研究了预时效处理对一种γ'相含量高达54%的高温合金的显微组织及其后续热变形行为的影响。为了获得可控的初始组织,对该合金在1090 °C至1130 °C的温度区间内进行了4小时的预时效处理。随后,在1050 °C和0.01 s⁻¹的应变速率条件下,对经过预时效处理的试样进行等温热压缩实验。结果表明,预时效处理成功地构建了由粗大的初生γ'相(γ'p)和细小的二次γ'相(γ's)组成的双峰γ'相结构。提高预时效温度导致了γ'p相的粗化(尺寸从300 nm增大至超过850 nm)以及γ's相的溶解,使得γ'相的总面积分数从约33%降低至约12%。在热压缩过程中,较高的预时效温度对应着较低的峰值流变应力,这表明材料的流动软化效应得到了改善。然而,研究发现预时效处理对动态再结晶(DRX)动力学产生了一种反常效应:较低的预时效温度反而促进了DRX的提前萌生,表现为更低的临界应变。这归因于大量细小的γ's相作为质点激发形核(PSN)的有效位点。相反,较高的预时效温度则因消除了这些形核位点而延迟并抑制了DRX过程。EBSD分析证实,由应变诱发晶界迁移(SIBGM)启动的非连续动态再结晶(DDRX)是主要的软化机制。本工作揭示了在高γ'相含量高温合金中,变形抗力与DRX动力学之间存在的关键制衡关系,为优化此类合金的热机械加工工艺提供了基础理论依据。

     

    Abstract: This study systematically investigated the influence of pre-aging treatments on the microstructure and subsequent hot deformation behavior of a superalloy with a 54% γ' content. Pre-aging was conducted for four hours at temperatures ranging from 1090 °C to 1130 °C to establish controlled initial microstructures. These were then subjected to isothermal hot compression at 1050 °C and a strain rate of 0.01 s⁻¹. The results demonstrated that pre-aging successfully created bimodal γ' structures, consisting of coarse primary (γ'p) and fine secondary (γ's) precipitates. Increasing the pre-aging temperature led to the coarsening of γ'p (from ~300 nm to >850 nm) and the dissolution of γ's, reducing the total γ' area fraction from ~33% to ~12%. During hot compression, a higher pre-aging temperature resulted in a lower peak flow stress, indicating improved flow softening. However, a counterintuitive effect on dynamic recrystallization (DRX) kinetics was observed: lower pre-aging temperatures promoted an earlier onset of DRX, evidenced by a lower critical strain. This was attributed to the dense population of fine γ's precipitates acting as potent sites for particle-stimulated nucleation (PSN). Conversely, higher pre-aging temperatures delayed and suppressed DRX by eliminating these nucleation sites. EBSD analysis confirmed that discontinuous dynamic recrystallization (DDRX), initiated by strain-induced grain boundary migration (SIBGM), was the dominant softening mechanism. This work reveals a critical trade-off between deformation resistance and DRX kinetics, providing a fundamental basis for optimizing the thermomechanical processing of superalloys with a high γ' fraction.

     

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