Fe元素对TC4钛合金熔化温度的影响

Influence of Fe on melting temperature of TC4 titanium alloy

  • 摘要: 航空用TC4钛合金薄壁件热处理过程中受工艺的影响易发生氧化和晶间腐蚀,若与其他材料接触加热,易与其中的Fe元素发生共晶反应,形成低熔点共晶产物在低温下熔化。研究不同材料中的Fe元素对TC4钛合金熔化温度的影响。选取Fe含量不同的典型航空材料GH4169、06Cr18Ni9和TC4钛合金板料进行研究,对比分析GH4169+TC4、06Cr18Ni9+TC4和GH4169+06Cr18Ni9共3组样品放置在真空气淬炉中进行1170℃保温40min热处理后的组织形态与共晶产物FeTi,使用布鲁克SITITAN 300光谱仪和Axio Observer蔡司显微镜对热处理产生的共晶产物FeTi成分进行分析。结果表明:当温度升至FeTi共晶温度点(最低共晶温度1085℃)时,不同样品中的Fe与TC4钛合金中的Ti在低熔点共晶区发生共晶反应,从而形成共晶化合物FeTi,Fe含量越高,反应越明显。随着温度升高,FeTi共晶组织发生熔化生成液相,从而降低TC4钛合金熔化温度。本研究可为航空用TC4钛合金零部件真空热处理提供理论指导。

     

    Abstract: During the heat treatment of thin walls of TC4 titanium alloy for aviation, the process affected is prone to oxidation and intercrystal corrosion. If heated with other materials, it is easy to cocrystalize with the Fe element in it, forming a low melting point eutectic reaction product that melts at low temperature. The purpose of this paper is to study the effect of Fe element in different materials on the melting temperature of TC4 titanium alloy. Select typical aviation materials with different Fe content of GH4169, 06Cr18Ni9 and TC4, and comparatively analyzed the tissue morphology and eutectic reaction product FeTi of the three groups of GH4169+TC4, 06Cro18Ni9+TC4 and GH4169+06Cr18Ni9 after being heat treated at 1170℃with a temperature of 40min. The composition of the eutectic product FeTi produced by heat treatment was analyzed using a Bruker Sititan 300 spectrometer and an Axio Observer Zeiss micrograph. The results showed that when the temperature rose to the FeTi cocrystallization temperature point(the minimum cocrystallizing temperature was 1085℃), The eutectic reaction between Fe and Ti in the low melting point eutectic region of TC4 titanium alloy occurs in different samples to form the eutectic reaction compound FeTi, the higher the Fe content, the more obvious the reaction. and as the temperature increased,the FeTi eutectic reaction organization melted to form a liquid phase, thereby reducing the melting temperature of the TC4 titanium alloy. This study can provide theoretical guidance for vacuum heat treatment of TC4 titanium alloy components used in aviation.

     

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